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28 D). Conversely to cobalt nanocrystals, “supra” crystals remain stable in time [22]. 5 Self-Assemblies in the Presence of External Forces and Constraints 2D hexagonal networks of nanocrystals and 3D fcc superlattices are the most commonly observed organizations with low-size-distribution nanocrystals. Furthermore, it was shown that the use of external force as in the Langmuir–Blodgett technique can improve the 2D hexagonal nanocrystal organization [100–103] and the monolayer is transferred on various substrates.

J. Am. Chem. Soc. 1997, 119, 2682. 54 Schaff T. , Hafigullin M. , Khoury J. ,Whetten R. , Cullen W. , First P. , Jose-Ycaman M. , J. Phys. Chem. B 1997, 101, 7885. , Gelbart W. , Heath J. , Adv. Mater. 1998, 10, 351. , Kiely C. , J. Chem. Mater. 1998, 10, 922. 57 Kiely C. , Schiffrin D. , Nature 1998, 396, 444. 58 Brown L. , Hutchison J. , J. Am. Chem. Soc. 1999, 121, 882. 59 Lin X. , Sorensen C. , J. Chem. Mater. 1999, 11, 198. 60 Whetten R. L, Shafigulin M. N, Khoury J. T, Alvarez M. , Acc.

E 2004, 69, 16304. 47 49 2 Structures of Magnetic Nanoparticles and Their Self-Assembly Zhong L. 1 Introduction Nanoparticles represent the most popular nanomaterials that have applications ranging from catalysts, surface coatings and drug delivery systems to composites. Structural characterization of nanoparticles relies on X-ray diffraction, optical spectroscopy, electron microscopy and scanning probe microscopy. As of today, transmission electron microscopy and its associated techniques are still the most powerful techniques for characterizing the structures of nanoparticles, and particularly in determining their shapes, sizes, size distribution and surface structures.

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A 10-point circle is associated with any general point of the ellipse. New properties of Fagnanos point by Ternullo M.

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